Humidity Sensing with PVA-Doped ZnO Nanocrystals: Synthesis, Characterization, and Performance Evaluation
DOI:
https://doi.org/10.32628/IJSRST2512202Keywords:
Thick Films, ZnO, Sensitivity, Humidity SensorsAbstract
The Synthesis, characterisation, and performance assessment of zinc oxide (ZnO) nanocrystals doped with polyvinyl alcohol (PVA) for use in humidity sensing are presented in this work. Sol-gel synthesis was used to create ZnO nanocrystals, which were then doped with different PVA concentrations to improve their hydrophilic characteristics and sensor responsiveness. Using scanning electron microscopy (SEM), and X-ray diffraction (XRD), the structural and morphological properties of the nanocrystals were investigated in detail. It was discovered that the addition of PVA affected the optical bandgap, surface morphology, and crystallinity of ZnO nanocrystals. Evaluations of the humidity detecting capabilities throughout a broad range of relative humidity (RH) levels (40–80%) demonstrated the PVA-doped ZnO sensors' increased sensitivity, quicker response/recovery times, and better repeatability when compared to their undoped counterparts. According to our results, PVA doping successfully modifies the surface characteristics of ZnO, which makes it a viable approach for creating effective and reasonably priced humidity sensors for industrial and environmental monitoring applications.
📊 Article Downloads
References
Soni, N., Dhariwal, N., Yadav, P. & Kumar, V. (2024). To study the enhanced humidity‑sensing performance of rGO/ZnO heterostructure compared to pure ZnO and its practical utility in contactless sensing device. Journal of Materials Science: Materials in Electronics, 35, 1521. DOI:10.1007/s10854-024-13281-1 DOI: https://doi.org/10.1007/s10854-024-13281-1
Kumari, A., Agarwal, A. & Sengupta, A. (2024). ZnO‑sputtered e‑textile for humidity sensing. MRS Fall Meeting, abstract SB10.07.04, 2024.
Tiwary, P., Mahapatra, R. & Chakraborty, A. K. (2024).Pyramid‑like ZnO microstructures as humidity sensor. Journal of Materials Science: Materials in Electronics. DOI: https://doi.org/10.1007/s10854-024-13090-6
Chen, C.‑H., Wu, J.‑F. & Lin, H.‑M. (2024). Synthesis of PANIHCl/ZnO conductive composite by in‑situ polymerization for humidity sensing application. Modern Physics Letters B. DOI: https://doi.org/10.1142/S0217984924410082
Man, J., Gu, W., Hu, Z., Dou, X. & Zhang, H. (2023).High‑performance ZnO humidity sensor synthesized by coprecipitation with PVP as surfactant for human respiration detection. Optoelectronics Letters, 19, 1–7. DOI: https://doi.org/10.1007/s11801-023-2105-2
Verma, R., Pathak, S., Dey, K. K. et al.(2022). Facile synthesized zinc oxide nanorod film humidity sensor based on variation in optical transmissivity. Nanoscale Advances, 4, 2902–2912. DOI: https://doi.org/10.1039/D1NA00893E
Gupta, P., Kumar, K., Saeed, S. H., Pandey, N. K., Verma, V., Singh, P. & Yadav, B. C.(2022). Influence of tin doping on LPG and humidity sensing properties of NiO nanoparticles. Journal of Materials Research, 37, 369–379. DOI: https://doi.org/10.1557/s43578-021-00418-9
Arote, S. A., Pathan, A. S., Hase, Y., Bardapurkar, P., Gapale, D. & Palve, B. M. (2019).Investigations on synthesis, characterization and humidity sensing properties of ZnO and ZnO–ZrO₂ composite nanoparticles prepared by ultrasonic assisted wet chemical method. Ultrasonics Sonochemistry, 55, 313–321. DOI:10.1016/j.ultsonch.2019.01.012 DOI: https://doi.org/10.1016/j.ultsonch.2019.01.012
Sharma, A., Kumar, Y., Mazumder, K., Rana, A. K. & Shirage, P. M.(2018). Controlled Zn₁₋ₓNiₓO nanostructures for an excellent humidity sensor and a plausible sensing mechanism. New Journal of Chemistry, 42, 8445–8457. DOI: https://doi.org/10.1039/C7NJ04801G
Shakya, V., Pandey, N. K., Misra, S. K. & Roy, A.(2017). Electrical and optical properties of ZnO–WO₃ nanocomposite and its application as a solid‑state humidity sensor. Bulletin of Materials Science, 40, 253–262. DOI: https://doi.org/10.1007/s12034-017-1373-5
Harith, Z. et al.(2015). Relative humidity sensor employing optical fibers coated with ZnO nanostructures. Indian Journal of Science and Technology, 8(35), 1–5. DOI:10.17485/ijst/2015/v8i35/85348 DOI: https://doi.org/10.17485/ijst/2015/v8i35/85348
Panda, S., Biswas, C. & Paul, K. S. (2015). One‑pot synthesis of mesoporous ZnO–SiO₂ nanocomposite as high performance humidity sensor. Colloids and Surfaces A, 483, 121–128.
Tomer, V. K., Duhan, S., Sharma, A. K. et al. (2015). One pot synthesis of mesoporous ZnO–SiO₂ nanocomposite as high‑performance humidity sensor. Colloids Surf. A, 483, 121–128. DOI: https://doi.org/10.1016/j.colsurfa.2015.07.046
Pandey, N. K., Tiwari, K. & Roy, A.(2012). ZnO–TiO₂ nanocomposite: characterization and moisture sensing studies. Bulletin of Materials Science, 35, 347–352. DOI:10.1007/s12034-012-0290-x DOI: https://doi.org/10.1007/s12034-012-0290-x
Yadav, B. C., Yadav, A. K. & Kumar,(2012) A. Effect of nanostructured ZnO additives on the humidity and temperature sensing properties of cuprous oxide. arXiv preprint arXiv:1205.2707. DOI: https://doi.org/10.1080/19430892.2012.706191
Pandey, N. K., Tripathi, A. & Tiwari, K.(2010). Review on moisture/humidity sensors based on ZnO composites. Sensor & Transducer, 122(9), 9–14.
Podila, R., Queen, W., Nath, A. et al.( 2010). Origin of ferromagnetic ordering in ZnO micro‑ and nanostructures. Nano Letters, 10(4), 1383–1386. DOI: https://doi.org/10.1021/nl1001444
Tripathi, A., Pandey, N. K., Tiwari, K. & Roy, A.(2009). Humidity sensing studies of WO₃–ZnO nanocomposite. Sensors & Transducers Journal, 104(5), 109–118.
Yadav, B. C., Awasthi, P., Mishra, A., Pandey, N. K. & Roy, A.(2007). ZnO–TiO₂ system: moisture sensing behaviour. Journal of Measurement Science and Technology, 18, 260–265.
Yadav, B. C., Pandey, N. K., Srivastava, A. & Sharma, P. (2007).Electrical humidity sensing behaviour of ZnO–TiO₂ nanocomposite. J. Measurement Science and Technology, 18, 260–265. DOI: https://doi.org/10.1088/0957-0233/18/1/032
Downloads
Published
Issue
Section
License
Copyright (c) 2025 International Journal of Scientific Research in Science and Technology

This work is licensed under a Creative Commons Attribution 4.0 International License.
https://creativecommons.org/licenses/by/4.0